Photochemical synthesis, structure and spectroscopic properties of [W(CO) 4 (C 5 H 10 N) 2 CH 2 ]
Inorganic Chemistry Communications(2014)
Abstract
Dipiperidylmethane (CH2dipip) coordinates to photochemically created W(CO)4 species to give a tungsten(0) complex [W(CO)4(CH2dipip)]. The structure of the new bidentate amine complex of tungsten(0) was established by spectroscopic methods (NMR, IR, UVVis) in solution and by single-crystal X-ray diffraction studies. A preliminary experiment indicates that the tungsten complex emits light at λmax.556nm, when it is excited by λmax.523nm in the solid state at room temperature.
MoreTranslated text
Key words
Tungsten,Chelating amine,Photolysis,NMR method,X-ray structure
AI Read Science
Must-Reading Tree
Example
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined