Synthesis and configuration of (1S,3R)- and (1R,3R)-1-(3,4-dimethoxyphenyl)-1,3-dimethyl-1,3-dihydroisobenzofurans

Irina N. Shishkina,Valeriya M. Demyanovich,Konstantin A. Potekhin,Atash V. Gurbanov,Nikolay S. Zefirov

Mendeleev Communications（2015）

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摘要

Cyclization of iodides of diastereomeric 1-(1-aryl-1-hydroxyethyl)-2-(1-trimethylammonioethyl)benzenes, derived from (S)-1-phenylethan- amine, proceeds diastereospecifically to afford (1S,3R)-and (1R,3R)-1-aryl-1,3-dimethyl-1,3-dihydroisobenzofurans, the potent antidepressants.

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