Synthesis, Characterization and DFT Studies of 1, 1′-Bis(diphenylphosphino)ferrocene Substituted Diiron Complexes: Bioinspired [fefe] Hydrogenase Model Complexes
Journal of chemical sciences/Proceedings of the Indian Academy of Sciences Chemical sciences(2015)
摘要
The reaction of [Fe2(CO)6(μ-toluene-3, 4-benzenedithiolate)] 1 and bidentate diphosphine, 1, 1′-bis(diphenylphosphino)ferrocene (dppf) has been studied. New complexes obtained have been characterized by various spectroscopic techniques as bioinspired models of the iron hydrogenase active site. The crystal structure of [Fe2(CO)5(κ 1-dppfO)(μ-toluene-3, 4-benzenedithiolate)] 4 is reported.
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关键词
Bioinorganic chemistry,hydrogenase enzyme,bidentate phosphine,proton reduction,redox active ligands,density functional calculations
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