Synthesis, Characterization and DFT Studies of 1, 1′-Bis(diphenylphosphino)ferrocene Substituted Diiron Complexes: Bioinspired [fefe] Hydrogenase Model Complexes

SANDEEP KAUR-GHUMAAN,A SREENITHYA,RAGHAVAN B SUNOJ

Journal of chemical sciences/Proceedings of the Indian Academy of Sciences Chemical sciences（2015）

引用 15|浏览4

暂无评分

摘要

The reaction of [Fe2(CO)6(μ-toluene-3, 4-benzenedithiolate)] 1 and bidentate diphosphine, 1, 1′-bis(diphenylphosphino)ferrocene (dppf) has been studied. New complexes obtained have been characterized by various spectroscopic techniques as bioinspired models of the iron hydrogenase active site. The crystal structure of [Fe2(CO)5(κ 1-dppfO)(μ-toluene-3, 4-benzenedithiolate)] 4 is reported.

查看译文

关键词

Bioinorganic chemistry,hydrogenase enzyme,bidentate phosphine,proton reduction,redox active ligands,density functional calculations

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要