Photoinduced electron transfer from zinc tetraphenylporphyrin to 2-nitrofluorene in polar solvent acetonitrile

Mihir Ghosh,Aruna K Mora,S Shashi Nath,P Hemant Kumar,Prakriti Ranjan Bangal,Subrata Sinha

Journal of Photochemistry and Photobiology A: Chemistry（2015）

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摘要

•Zinc tetraphenylporphyrin-2-nitroflurne system is studied for electron transfer.•Observations indicate significant intermolecular photoinduced electron transfer.•Observed fluorescence quenching rates are in good agreement with Marcus theory.•Femtosecond transient absorption data show formation of charge separated state.

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关键词

Zinc tetraphenylporphyrin,2-Nitrofluorene,Electron transfer,Marcus theory

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