Syntheses and stimuli-responsible rocking motions of a rotaxane bearing different stoppers

Keiji Hirose, Shizuka Okada,Shota Umezaki,Philip G Young,Yoshito Tobe

Journal of Photochemistry and Photobiology A: Chemistry（2016）

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Abstract

•A rotaxane composed of a ring having a metaphenylene which swings was synthesized.•The rates of the rocking were switched in response to photo- and thermal-stimuli.•The rates of the rocking changed substantially by changing the size of the ring unit.

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Key words

Photocycloaddition,Molecular switch,Rocking dynamics,Molecular machines,Rotaxanes,Crown compounds

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