Conversion Of Two Eremophilane Glucosides From Pittocaulon Praecox Into Eremophilanolides
Heterocycles(2012)
摘要
Two eremophilanolides (3, 4), an aldehyde (6), an intramolecular addition product (7), and two water addition products (8, 9) were obtained by acid treatment of the eremophilane glucosides 10 and 11. A reaction mechanism supported by deuterium labeling is proposed for the conversion of eremophilane glycosides into eremophilanolides.
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关键词
Eremophilane Transformation,Deuterium Labeling,Eremophilanolide
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