Infrared overtone spectroscopy of adsorbed hydrogen in MOF-5

Stephen A. FitzGerald,Jocienne N. Nelson,Elizabeth Gilmour,Jesse L.C. Rowsell

Journal of Molecular Spectroscopy（2015）

引用 6|浏览16

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摘要

•IR overtone spectroscopy is shown to aid the identification of obscured modes.•The (ro)vibrational modes of D2 and HD adsorbed in MOF-5 are observed.•Overtone bands of H2 at primary adsorption site are greatly enhanced.•Q2(0) is significantly enhanced compared to other overtone modes.•Enhancement is attributed to coupling to a MOF carboxylate stretch mode.

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关键词

Infrared,Overtone,Spectroscopy,Hydrogen storage,Metal–organic frameworks,MOF-5,Mode coupling

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