X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF HEXAMERIC "DI-TERT-BUTYLMETHYLENEAMINOLITHIUM, (LIN=CBU-TERT-2)6 - ELECTRON-DEFICIENT BRIDGING OF LI-3 TRIANGLES BY METHYLENEAMINO NITROGEN-ATOMS

HMM SHEARER,K WADE, G WHITEHEAD

Journal of The Chemical Society, Chemical Communications（1979）

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摘要

An X-ray crystallographic study of the title compound, (LiNCBut2)6, has revealed a ‘folded chair’ arrangement of its metal atoms held together by triply bridging methyleneamino groups in what is believed to be the first example of electron-deficient bridging through the nitrogen atom of an organonitrogen ligand.

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nitrogen,molecular structure

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