BIOSYNTHESIS OF VITAMIN-B12 - SYNTHESIS OF (+-)-[5-C-13]FAKTOR-1 ESTER - DETERMINATION OF THE OXIDATION-STATE OF PRECORRIN-1

RD BRUNT,FJ LEEPER,I GRGURINA,AR BATTERSBY

Journal of The Chemical Society, Chemical Communications（1989）

引用 21|浏览1

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摘要

(±)-[5-13C]Faktor-1 ester is synthesised following an east–west disconnection strategy and is used to show by specific enzymic incorporation experiments that the first C-methylation product, precorrin-1, on the B12-biosynthetic pathway is a tetrahydrochlorin.

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关键词

vitamin,biosynthesis,oxidation

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