Enhancing the carbon capture capacities of a rigid ultra-microporous MOF through gate-opening at low CO2 pressures assisted by swiveling oxalate pillars.
CHEMICAL COMMUNICATIONS(2016)
摘要
Porosity enhancement assisted by an unusual gate opening has been realized in an exceptionally rigid ultra-microporous framework. The gate-opening has been attributed to the presence of symmetrically positioned Zn-O bonds of the Zn-oxalate units that facilitate subtle swiveling motion resulting in a drastic improvement (42%) in the CO2 capacity without compromising the CO2/N-2 selectivity.
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关键词
carbon capture capacities,low co<sub>2</sub>pressures,ultra-microporous,gate-opening
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