On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes

Christian R Parker,Kasper Lincke,Mikkel A Christensen,Karol Lušpai,Peter Rapta,Thomas Just Sørensen,Thorbjørn J Morsing,Lin Du,Henrik G Kjaergaard,Ole Hammerich,François Diederich,Mogens Brøndsted Nielsen

Organic & Biomolecular Chemistry（2016）

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摘要

Here, we report the first X-ray crystal structure of a tetrathiafulvalene- fused dehydroannulene with peripheral ethylthio substituents. In addition, we have subjected this compound to electrochemical and UV-Vis-NIR/ESR spectroelectrochemical studies to elucidate the degree to which the oxidised species associate.

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关键词

Tetrathiafulvalene Chemistry,Metal Dithiolene Complexes

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