Sultones and Sultines via a Julia-Kocienski Reaction of Epoxides.

Geoffrey M T Smith,Paul M Burton,Christopher D Bray

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2015）

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摘要

The development of the homologous Julia-Kocienski reaction has led to the discovery of two new reaction modes of epoxides with sulfones. These pathways allow rapid and direct access to a range of gamma-sultones and gamma-sultines.

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关键词

anion-relay,anions,spiro compounds,sulfur heterocycles,synthetic methods

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