Why p-Cymene? Conformational effect in asymmetric hydrogenation of aromatic ketones with a η(6) -arene/ruthenium(II) catalyst.

Aki Matsuoka,Christian A Sandoval,Masanobu Uchiyama,Ryoji Noyori,Hiroshi Naka

CHEMISTRY-AN ASIAN JOURNAL（2015）

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摘要

The global reaction route mapping (GRRM) methods conveniently define transition states in asymmetric hydrogenation and transfer hydrogenation of aromatic ketones via the [RuH{(S,S)-TsNCH(C6H5)CH(C6H5)NH2}((6)-p-cymene)] intermediate. Multiple electrostatic CH/ interactions are the common motif in the preferred diastereometric structures.

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关键词

asymmetric catalysis,CH,interaction,density functional calculations,hydrogenation,ruthenium

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