A convergent synthesis of the fully elaborated macrocyclic core of TMC-95A.
ORGANIC LETTERS(2014)
摘要
A concise and straightforward synthesis of the fully elaborated macrocyclic core of TMC-95A is reported. A highly efficient organocatalyzed aldolization between isatin and dihydroxyacetone derivatives and formation of the biaryl subunit with concomitant macrocyclization are the characteristic features of this synthesis.
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关键词
elaborated macrocyclic core,convergent synthesis
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