Tuning reactivity of glycosyl imidinium intermediate for 2-azido-2-deoxyglycosyl donors in α-glycosidic bond formation.

Arun B Ingle,Chin-Sheng Chao,Wei-Cheng Hung,Kwok-Kong Tony Mong

ORGANIC LETTERS（2013）

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摘要

The chemical properties of nucleophile additives were investigated in a modulated glycosylation context. N-Formylmorpholine (NFM) was found to be an effective modulator for glycosylation with less reactive 2-azido-2-deoxythioglucosyl and thiogalactosyl donors.

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关键词

Glycosylation Mechanisms,Glycosylation

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