Formation of low density hydrous iron oxide via conformal transformation of MIL-53(Fe).

Talha J Pirzada,Stuart A MacGregor,Safeer Ahmed,Karen J Edler,Harina Amer Hamzah,Dongmei Jiang,Andrew D Burrows,John M Mitchels,Ibrahim A I Hassan,Jonathan E Halls,Frank Marken

CHEMICAL COMMUNICATIONS（2014）

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摘要

Hydrous iron oxide materials with a predefined shape, photo-electrochemical activity, low density (estimated to be 0.32 g cm(-3)), and high fractal porosity (BET ca. 117 m(2) g(-1)) are formed via internal hydrolytic transformation of the crystalline metal-organic framework MIL-53(Fe) in dilute aqueous hydroxide.

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关键词

hydrous iron oxide,mil-53fe,conformal transformation

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