Analysis of anabolic steroids in urine by gas chromatography-microchip atmospheric pressure photoionization-mass spectrometry with chlorobenzene as dopant.

Journal of Chromatography A(2013)

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摘要
•Photoionization is used to connect GC to MS.•A novel microchip is the key component in GC–μAPPI-MS.•Radical cations are produced with minimal fragmentation, unlike in GC–EI-MS.•GC–μAPPI-MS is proven highly sensitive and applicable for doping control.
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关键词
Atmospheric pressure photoionization,Tandem mass spectrometry,Gas chromatography,Microchip,Anabolic steroids,Doping control
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