Dodecanuclear Hexagonal-Prismatic M12l18 Coordination Cages By Subcomponent Self-Assembly
INORGANIC CHEMISTRY(2013)
摘要
Dodecanuclear hexagonal-prismatic M12L18 cages were prepared by a subcomponent self-assembly process with commercially available pyridinecarboxaldehyde, m-xylenediamine, and cadmium(II) perchlorate or manganese(II) perchlorate. The NMR spectrum of the Cd cage shows that there are three independent ligand sets, and the X-ray crystal structure of the Mn cage reveals that the structure has both fac-Delta- and mer-Lambda-configured metal centers in a 1:1 ratio. The cage structure also has a large cavity that contains five perchlorate anions.
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关键词
coordination cages,hexagonal-prismatic,self-assembly
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