Aluminum, Gallium, Germanium, Copper, And Phosphorus Complexes Of Meso-Triaryltetrabenzocorrole
INORGANIC CHEMISTRY(2013)
摘要
5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV-vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the pi-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.
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关键词
Metal Complexes,Room-Temperature Phosphorescence,High-Spin Transition Metal Complexes
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