Cross-hyperconjugation: an unexplored orbital interaction between π-conjugated and saturated molecular segments.

Durchlässige Grenze: Moleküle, in denen gesättigte ER2-Einheiten (E=C oder Si, R=elektronenschiebende Gruppe) zwischen zwei konjugierten π-Systemen eingeschoben sind, zeigen ähnliche elektronische und optische Eigenschaften wie kreuzkonjugierte Moleküle (siehe Bild). Diese Kreuz-Hyperkonjugation bildet eine Alternative zur Kreuzkonjugation beim Entwurf von Molekülen für Nanostrukturen und Materialien. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.