A heteropolytungstate based 2D layered porous framework with high proton conductivity

Mengnan Yang, Yao Zhang,Shiyan Ji,Huafeng Li,Xinyi Ma,Yuzhen Jin,Pengtao Ma,Jingping Wang,Jingyang Niu

Chemical communications (Cambridge, England)（2023）

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摘要

A heteropolytungstate cluster [{RuO(bpy)}{BiWO}] (bpy = CHN) was incorporated into a 2 : 1 type layered porous framework by interweaving the Na bridged cluster chains through the hydrogen bonding ability of the bpy ligands. It features multiple pore channels rich in hydrogen-bond network, contributing high conductivities > 10 S cm at 298-358 K and 85% RH.

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关键词

porous framework,heteropolytungstate,conductivity

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