Dehydration of highly concentrated solutions of fructose to 5-hydroxymethylfurfural in a cheap and sustainable choline chloride/carbon dioxide system.

CHEMSUSCHEM(2012)

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摘要
Fête DES sciences: The dehydration of fructose and inulin to HMF is conveniently performed in a cheap and sustainable choline chloride/CO(2) deep eutectic solvent (DES) system. The medium is capable of converting high contents of fructose (>100 wt %) without affecting the yield of HMF (up to 72 %). The purity of the recovered HMF is >98%, and the reaction medium can be recycled.
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关键词
biomass,carbohydrates,carbon dioxide,catalysis,renewable resources
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