Chloroheptakis(dimethyl sulfoxide)uranium(IV) trichloride

Oldham Warren J,Scott Brian L,Abney Kent D,Smith Wayne H,Costa David A

Acta Crystallographica Section C-crystal Structure Communications（2002）

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摘要

In the title complex, [UCl(C2H6OS)(7)]Cl-3, the uranium metal center is coordinated in a distorted bicapped trigonal prism geometry by seven O atoms from dimethyl sulfoxide ligands and by a terminal chloride ligand. Charge balance is maintained by three outer-sphere chloride ions per uranium(IV) metal center. Principle bond lengths include U-O 2.391 (2)-2.315 (2) Angstrom, U-Cl 2.7207 (9) Angstrom, and average S-O 1.540 (5) Angstrom.

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