Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C(sp)-P bond formation.

Ibrahim Abdellah,Elise Bernoud,Jean-François Lohier,Carole Alayrac,Loïc Toupet,Christine Lepetit,Annie-Claude Gaumont

CHEMICAL COMMUNICATIONS（2012）

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摘要

Copper-phosphido-borane complexes were synthesized and isolated for the first time. Their structures were experimentally and computationally investigated. They were shown to display catalytic activity in C-sp-P bond formation.

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