On the Geometry of the CuCl(2) Molecule.

I. R. Beattie,J. M. Brown,P. Crozet,A. J. Ross,A. Yiannopoulou

Inorganic chemistry（1997）

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摘要

High-resolution laser-induced fluorescence spectroscopy coupled with isotopic substitution shows that the molecule CuCl2 has a linear 2Πg(3/2) ground state with a Cu−Cl interatomic distance of 203.52 pm. Values for the harmonic wavenumbers ω1, ω2, and ω3 are reported, together with a number of rotational and anharmonicity constants.

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