New insights into the biological and synthetic fixation of nitrogen.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2012)
摘要
The fixation with fixation: Microorganisms have converted atmospheric nitrogen into ammonia for millions of years under ambient conditions, whereas the Haber–Bosch process requires high pressures and temperatures. Some recent studies on the biological and synthetic generation of ammonia should contribute to a better understanding of the mechanism of this reaction, which remains one of the most challenging goals for catalysis.
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关键词
ammonia,Haber-Bosch process,iron,nitrogen fixation,nitrogenase
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