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A caged cyanide

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES(2012)

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摘要
A photoactivatable caged cyanide, 1-(2-nitrophenyl)ethyl (NPE) cyanide, was synthesized, which upon irradiation in the near UV releases cyanide. It is demonstrated that the compound can be used to induce formation of the Fe III –CN - complex in the heme protein nitrophorin 4 from Rhodnius prolixus .
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