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An unsymmetrical bis C-C agostic heterobimetallic lithium yttrium complex.

Yannick Escudié,Chiara Dinoi,Olivia Allen,Laure Vendier,Michel Etienne

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2012）

Cited 19|Views3
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Abstract
Two better than one! The structural distortions in a bis(cyclopropyl) heterobimetallic lithium yttrium complex can be interpreted as two types of CC agostic interactions (see structure), one with a more covalent character with Y, the other with a more electrostatic character with Li. The CC agostic interaction with Y is reinforced by a CH agostic interaction.
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Key words
agostic interactions,density functional calculations,lithium,structure elucidation,yttrium
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