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Stable fluorophosphines: predicted and realized ligands for catalysis.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2012)

Cited 47|Views26
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Abstract
Ligandenkarte führt zum Schatz! Mithilfe einer Ligandenkarte lässt sich die Aktivität von Komplexen mit Fluorphosphanen (R2PF) in der katalytischen Hydroformylierung und Hydrocyanierung vorhersagen. Beispiele von R2PF-Liganden (siehe Schema) werden beschrieben, die gegen Disproportionierung stabilisiert sind, sodass sie in sehr effizienten Katalysen eingesetzt werden können. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Key words
homogeneous catalysis,hydrocyanation,hydroformylation,phosphacycles,phosphane ligands
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