Highly enantioselective rhodium-catalyzed asymmetric 1,4-addition reactions of arylboronic acids to acyclic α,β-unsaturated compounds: the formal synthesis of (-)-indatraline.
CHEMISTRY-A EUROPEAN JOURNAL（2011）
Abstract
Chiral 2,5-disubstituted bicyclo[2.2.1]heptadiene ligands are prepared and applied to the conjugate addition reaction of arylboronic acids to acyclic α,β-unsaturated compounds.
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Key words
addition reactions,arylboronic acids,asymmetric catalysis,diene ligands,enantioselectivity,indatraline,rhodium
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