Irreversible solvent-driven conversion in cyanometalate {Fe2Ni}n (n=2, 3) single-molecule magnets.

Yuan-Zhu Zhang,Uma P Mallik,Rodolphe Clérac,Nigam P Rath,Stephen M Holmes

CHEMICAL COMMUNICATIONS（2011）

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摘要

Two cyano-bridged single-molecule magnets of {(Fe4Ni2II)-Ni-III} and {(Fe6Ni3II)-Ni-III} stoichiometry are described via their magnetic properties described in the frame of geometrical core distortions and orientations of their local anisotropy axes.

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