Large-scale synthesis of all stereoisomers of a 2,3-unsaturated C-glycoside scaffold.
JOURNAL OF ORGANIC CHEMISTRY(2011)
摘要
All stereoisomers of a highly functionalized 2,3-unsaturated C-glycoside can be accessed in 10-100 g quantities from readily available starting materials and reagents in 3-7 steps. These chiral scaffolds contain three stereogenic centers along with orthogonally protected functional groups for downstream reactivity.
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关键词
glycosides,stereoisomerism
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