Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes with Arylamines.

SYNLETT(2010)

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摘要
A mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgOTf catalyzes the intermolecular hydroamination of monosubstituted and 1,1- and 1,3-disubstituted allenes with primary and secondary arylamines.
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关键词
allylations,allenes,amines,homogenous catalysis,regioselectivity
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