Double loading of ZnCl(2) by polytopic ligands which co-extract Zn(2+) and tetrachloridozincate.
DALTON TRANSACTIONS(2010)
摘要
Combining cation-and anion-binding functionalities in a salen-type extractant leads to multiple loading of ZnCl2. Zn(II) cations are bound by the salen N2O22- donor set, and chlorozincate anions are associated with protonated pendant amine groups.
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关键词
zncl2,polytopic ligands,co-extract
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