A hydridoirida-beta-diketone as an efficient and robust homogeneous catalyst for the hydrolysis of ammonia-borane or amine-borane adducts in air to produce hydrogen.

Roberto Ciganda,María A. Garralda,Lourdes Ibarlucea,Elena Pinilla,M. Rosario Torres

DALTON TRANSACTIONS（2010）

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摘要

The first homogeneous metal-catalysed hydrolysis of ammonia-borane or amine-borane adducts for hydrogen generation, using a stable organometallic complex[IrHCl{(PPh2(o-C6H4CO))(2)H}], is reported.

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