An MNDO approach to the symmetry of bromine bridging in substituted bromonium ions
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS(1990)
摘要
Calculated energy profiles for the opening of six methyl bromonium ions show single, shallow or very flat minima corresponding to symmetrical or highly asymmetrical bridged structures depending on the symmetry of the substitution but not on the number of methyl groups.
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关键词
bromine,mndo approach,ions
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