Total synthesis of pachastrissamine together with its 4-epi-congener via [3,3]-sigmatropic rearrangements and antiproliferative/cytotoxic evaluation.

Carbohydrate Research(2015)

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摘要
•The total synthesis of pachastrissamine and its 4-epi-congener was accomplished.•The cornerstone of this strategy was a [3,3]-heterosigmatropic rearrangement.•Crystallographic analysis of a key structure was performed.•A series of synthesized compounds was evaluated for the anticancer activity.
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关键词
Anhydrophytosphingosines,Jaspine B,Pachastrissamine,[3,3]-Heterosigmatropic rearrangements,Stereoselective synthesis,Anticancer activity
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