Synthesis of norcantharidin-dimer derivatives
JOURNAL OF HETEROCYCLIC CHEMISTRY(2011)
Abstract
We use one molecule of ethylene diamine as a connecting arm to combine two molecules of 5,6-dehydronorcantharidin. Then, ten novel norcantharidin derivatives were synthesized in a single step by the [3 + 2] 1,3-dipolar cycloaddition reaction with oxime or hydrazone in the presence of chloramine-T, which is simpler than the conventional method.
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Key words
synthesis,cheminform abstract,norcantharidin-dimer
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