25℃时三元体系SrCl2-CaCl2-H2O相平衡研究
Chinese Journal of Inorganic Chemistry（2011）
Abstract
采用等温溶解平衡法,研究了三元体系SrCl2-CaCl2-H2O 25℃相平衡,同时测定了平衡溶液的物化性质(密度和折光率).平衡液相所对应的平衡固相由湿渣法、偏光显微镜观测法和XRD法确定.根据实验研究数据,绘制了该三元体系相图.相图由3个无变量点、4条单变量曲线和4个盐类结晶区构成,4个结晶区分别对应CaCl2·6H2O、钙盐为基固溶体、锶盐为基固溶体和SrCl2·6H2O结晶区.
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Key words
Calcium chloride,Phase equilibrium,Solid solution,Solubility,Strontium chloride
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