Mild and efficient iodine-catalyzed direct substitution of hydroxy group of alcohols with c- and n-nucleophiles
LETTERS IN ORGANIC CHEMISTRY(2011)
摘要
A mild and efficient iodine-catalyzed direct substitution of hydroxy group of allylic, progargylic and other alcohols with various C-and N-nucleophiles was described in this contribution. C-C and C-N bond formations could be readily achieved by non-metallic and green catalysis for various compounds. This facilitates access to possible transformations of a broad scope of substrates into bioactive and pharmaceutically important building blocks.
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关键词
Allylation,Bond formation,C-,N-nucleophiles,Green chemistry,Iodine,Isomerization,Propargylation,Substitution
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