(E)-1-[(2-Chloro-5-methyl-pyridin-3-yl)methyl-ene]thiosemicarbazide.

Acta crystallographica. Section E, Structure reports online(2010)

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Abstract
The title compound, C(8)H(9)ClN(4)S, which has potential insecticidal activity, was synthesized by the reaction of 2-chloro-5-methyl-nicotinaldehyde and thio-semicarbazide. In the crystal structure, the mol-ecules are linked via inter-molecular N-H⋯N, N-H⋯S and N-H⋯Cl hydrogen bonds, forming a three-dimensional network stacked down a.
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data-to-parameter ratio = 14.3,mean σ(c-c) = 0.004 å,r factor = 0.037,single-crystal x-ray study,t = 173 k,wr factor = 0.105
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