Indium Chalcogenido Clusters Coordinated By 1,10-Phenanthroline, [Inq(Phen)Cl](4) (Q = Se, S), A Simplified Model Of Inorganic-Organic Hybrid Material With Cluster-To-Ligand Charge Transfer

Most metal-1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused with moieties of the phen complex and inorganic chalcogenide. Compounds 1 and 2 are new types of cubic clusters with cluster-to-ligand charge transfer.