[1,2-Bis(diphenylphosphino)ethanej 2P,P00] (2-carboxyl-atothio-phenolato- 2 O,S)nickel(II) methanol solvate

Acta Crystallographica Section E: Structure Reports Online(2009)

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摘要
In the title complex, [Ni(C7H4O2S)(C26H24P2)]·CH3OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio-salicylate ligand and the two P atoms of the chelating Ph2PCH2CH2PPh2 ligand. There is hydrogen bonding between the methanol solvent mol-ecule and the carbonyl O atom of the thio-salicylate ligand.
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