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二甲基苯酚钾作助引发剂的烯烃阴离子调节聚合

Yan REN,Yu-rong WANG,Hai-feng LIU,Chun-qing LIN,Chun-qing ZHANG

Zhongshan Daxue Xuebao/Acta Scientiarum Natralium Universitatis Sunyatseni（2005）

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Abstract
采用合成时环境友好,在四氢呋喃中溶解性良好的二甲基苯酚钾作助引发剂,正丁基锂为引发剂、二甲苯为溶剂兼作链转移剂、2G为极性调节剂对二烯烃阴离子调聚进行了研究.考察了不同D-ROK / n-BuLi 对聚合物的特性粘度、分子量、分子量分布及微观结构的影响关系.制得的液体聚丁二烯和聚异戊二烯可用作绿色涂料的原料.
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Key words
Chain transfer number,Green coating,Liquid rubber,Microstructure,Relative molecular mass
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