Enantioselective Total Synthesis of 12-Carboxyeudesma-3, 11 (13)-diene
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE(2002)
Abstract
The enantioselective total synthesis of 12-carboxyeudesma-3,11(13)-diene (1) was achieved starting from (-)-dihydrocarvone in ten steps for the first time. The key steps mainly include the introduction of hydroxyl group into C-12 position of eudesmane by Vilsmeier chlorination and the generation of C3-C4 double bond into the eudesmane skeleton by elimination of halide.
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Key words
12-carboxyeudesma-3,11(13)-diene,enantioselective total synthesis,(-)-dihydrocarvone
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