β-二酮钛非茂催化剂催化降冰片烯聚合
Acta Polymerica Sinica（2001）
Abstract
用(dibenzoylmethanato)2Ti(OPh)2[(dbm)2-Ti(OPh)2]/甲基铝氧烷(MAO)为代表的新型β-二酮钛非茂催化剂实现了降冰片烯的聚合,得到加成聚合和开环易位聚合的混合物,研究了实现高聚合活性所需的特殊条件及所得的聚合物结构,主要应用傅立叶转变红外技术(FTIR)对聚合物结构进行了表征和分析.
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Key words
β-diketonate titanium,Non-metallocene catalysts,Polynorbomene
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