A New Rearrangement Reaction Of 2-Phenyl Substituted Benzothiazepine With Ethoxycarbonyl Carbene - Mechanism Of The Reaction And Structure Of The Product
CHINESE CHEMICAL LETTERS（1999）
Abstract
2,3-Dihydro-2-phenyl-4-(4-methoxyphenyl)-1,5-benzothiazepine reacts with ethoxycarbonyl carbene to give an unexpected compound 2,3-disubstituted-4H-1,4-benzothiazine III. It was found to be a new rearrangement reaction and the structure of the product was confirmed by IR, NMR, MS.
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Key words
benzothiazepine, ethoxycarbonyl carbene, rearrangement reaction
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