The Activation And Carbonylation Of The C-Cl Bond Catalyzed By Transition-Metal Complexes

Wei Zhong Zheng,Wen Wan,FuJiang Ding,LiangFu Zhang

CHINESE CHEMICAL LETTERS（1998）

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摘要

Diethyl malonate was synthesized by transition-metal catalyzed alkoxycarbonylation of ethyl chloroacetate. The results show that the conversion of ethyl chloroacetate is greater than 92%, and the selectivity to diethyl malonate is 67.5%.

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关键词

carbonylation, transition-metal complexes, catalysis

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