Regioselective Etherification Of 1,2-O-Isopropylidene-4,6-Di-O-Benzyl Myo-Inositol
CHINESE JOURNAL OF CHEMISTRY（1996）
Abstract
During the etherification of 1,2-O-isopropylidene-4,6-di-O-benzyl myo-inositol, the specific regioselectivity on 3- or 8-hydroxyl group was showed to be determined by the nature of the O-alkylating agents used. As demonstrated by MM and MNDO calculation, the regioselectivity of the reaction mentioned can be rationalized by steric and/or electronic effect.
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Key words
regioselective, etherification, myo-inositol, MM and MNDO calculation
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