[FeIV(Oanti/syn)(TMC)(Lax)]n+ for O-transfer Reaction: insight into the steric hindrance effect of the equatorial ligand

Yi Wang,Zixian Li,Chenhao Li,Yutai Qi,Qingyue Li,Peng Zhang

Chemical Physics Letters（2020）

引用 1|浏览7

暂无评分

摘要

•Expect syn-AN, the ligand topology exhibits little effect on the reactivity.•Along the reaction pathway, the AN ligand is away from the iron center.•The relative reactivity of the O-transfer reaction follows the order: syn-AN > syn-TF > syn-N3 > syn-SR.

查看译文

关键词

Non-heme,Steric hindrance,O-transfer,DFT,Syn and anti

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要